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Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Rekke forfattare: 22016 (engelsk)Inngår i: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 45, nr 37, s. 14421-14461Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Catalysts for the oxidation of H2O are an integral component of solar energy to fuel conversion technologies. Although catalysts based on scarce and precious metals have been recognized as efficient catalysts for H2O oxidation, catalysts composed of inexpensive and earth-abundant element(s) are essential for realizing economically viable energy conversion technologies. This Perspective summarizes recent advances in the field of designing homogeneous water oxidation catalysts (WOCs) based on Mn, Fe, Co and Cu. It reviews the state of the art catalysts, provides insight into their catalytic mechanisms and discusses future challenges in designing bioinspired catalysts based on earth-abundant metals for the oxidation of H2O.

sted, utgiver, år, opplag, sider
2016. Vol. 45, nr 37, s. 14421-14461
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Identifikatorer
URN: urn:nbn:se:su:diva-135080DOI: 10.1039/c6dt00809gISI: 000384404700002PubMedID: 27142095OAI: oai:DiVA.org:su-135080DiVA, id: diva2:1049020
Tilgjengelig fra: 2016-11-23 Laget: 2016-10-31 Sist oppdatert: 2017-11-29bibliografisk kontrollert

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