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Methyl 3-O-α-l-fucopyranosyl β-d-glucopyranoside tetrahydrate
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
2012 (engelsk)Inngår i: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. 68, s. o3180-o3181Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The title compound, C13H24O10·4H2O, is the methyl glycoside of a disaccharide structural element present in the backbone of the capsular polysaccharide from Klebsiella K1, which contains only three sugars and a substituent in the polysaccharide repeating unit. The conformation of the title disaccharide is described by the glycosidic torsion angles ϕH = 51.1 (1)° and ψH = 25.8 (1)°. In the crystal, a number of O—HO hydrogen bonds link the methyl glycoside and water mol­ecules, forming a three-dimensional network. One water mol­ecule is disordered over two positions with occupancies of 0.748 (4) and 0.252 (4).

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2012. Vol. 68, s. o3180-o3181
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URN: urn:nbn:se:su:diva-85930DOI: 10.1107/S1600536812041992OAI: oai:DiVA.org:su-85930DiVA, id: diva2:585538
Forskningsfinansiär
Swedish Research CouncilTilgjengelig fra: 2013-01-10 Laget: 2013-01-10 Sist oppdatert: 2017-12-06bibliografisk kontrollert

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Eriksson, LarsWidmalm, Göran
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