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Mechanistic investigation on the hydrogenation of imines by [p-(Me2CH)C6H4Me]RuH(NH2CHPhCHPhNSO2C6H4-p-CH3). Experimental support for an ionic pathway.
2006 (engelsk)Inngår i: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, nr 26, s. 2771-2773Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The need for acidic activation in the stoichiometric hydrogenation of benzyl-[1-phenyl-ethylidene]-amine (6a) or [1-(4-methoxy-phenyl)-ethylidene]-methyl-amine (6b) by Noyori's catalyst [p-(Me2CH)C6H4Me]RuH(NH2CHPhCHPhNSO2C6H4-p-CH3) (2) is inconsistent with the proposed concerted mechanism and supports an ionic mechanism. [on SciFinder(R)]

sted, utgiver, år, opplag, sider
2006. nr 26, s. 2771-2773
Emneord [en]
mechanism hydrogenation imine ruthenium complex catalyst
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Identifikatorer
URN: urn:nbn:se:uu:diva-174518DOI: 10.1039/b605838hOAI: oai:DiVA.org:uu-174518DiVA, id: diva2:527601
Merknad
CAPLUS AN 2006:639871(Journal)Tilgjengelig fra: 2012-05-21 Laget: 2012-05-21 Sist oppdatert: 2017-12-07

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Samec, Joseph S. M.
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