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The application of reversible covalent bonds in catalysis
KTH, Skolan för kemivetenskap (CHE).
2014 (engelsk)Independent thesis Advanced level (professional degree), 20 poäng / 30 hpOppgave
Abstract [en]

This work has been concerned with the study of ligand exchange of trimethylborate and its  ability to induce temporary intramolecularity. Experiments aimed at understanding the affinity of various alcohols and amines to boron centers by studying the formation of mixed borate species during equilibrium. Furthermore, a variety of reactions has been screened with the aim to perform catalysis by induced intramolecularity through the trimethylborate.

Abstract [sv]

I detta projekt har ligandutbyte på trimetylborat, samt dess möjlighet att inducera intramolekularitet studerats. Experiment har utförts som inriktats på en fördjupad förståelse för boraffiniteten hos alkoholer och aminer, samt jämvikterna i dessa system. Vidare har reaktioner screenats i sökandet efter en reaktion som kan katalyseras av inducerad intramolelcularitet av trimetylborat.

sted, utgiver, år, opplag, sider
2014.
Emneord [en]
Induced intramolecularity, tethering, trimethylborate, catalysis, NMR-study
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-145952OAI: oai:DiVA.org:kth-145952DiVA, id: diva2:721108
Tilgjengelig fra: 2014-06-03 Laget: 2014-06-03 Sist oppdatert: 2014-06-03bibliografisk kontrollert

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