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Chemical and Photochemical Water Oxidation Mediated by an Efficient Single-Site Ruthenium Catalyst
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Vise andre og tillknytning
2016 (engelsk)Inngår i: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 9, nr 24, s. 3448-3456Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Water oxidation is a fundamental step in artificial photosynthesis for solar fuels production. In this study, we report a single-site Ru-based water oxidation catalyst, housing a dicarboxylate-benzimidazole ligand, that mediates both chemical and light-driven oxidation of water efficiently under neutral conditions. The importance of the incorporation of the negatively charged ligand framework is manifested in the low redox potentials of the developed complex, which allows water oxidation to be driven by the mild one-electron oxidant [Ru(bpy)(3)](3+) (bpy = 2,2'-bipyridine). Furthermore, combined experimental and DFT studies provide insight into the mechanistic details of the catalytic cycle.

sted, utgiver, år, opplag, sider
2016. Vol. 9, nr 24, s. 3448-3456
Emneord [en]
electrochemistry, homogeneous catalysis, photochemistry, ruthenium, water oxidation, GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-141313DOI: 10.1002/cssc.201601171ISI: 000394571500013PubMedID: 27966290OAI: oai:DiVA.org:su-141313DiVA, id: diva2:1086634
Forskningsfinansiär
Swedish Research CouncilKnut and Alice Wallenberg FoundationCarl Tryggers foundation Tilgjengelig fra: 2017-04-03 Laget: 2017-04-03 Sist oppdatert: 2017-06-27bibliografisk kontrollert

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Abdel-Magied, Ahmed F.Shatskiy, AndreyLiao, Rong-ZhenLaine, Tanja M.Siegbahn, Per E. M.Kärkäs, Markus D.Åkermark, BjornJohnston, Eric V.
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